Kinetic of Catalytic CO2Gasification for Cyprus Coal by Gas-Solid Reaction Model

Gas-Solid Catalytic Reactions

The outline of this chapter is as follows: *.1 will show some application areas together with the number of types of reactors available for carrying out gas-solid catalyzed reactions. Section *.2 will focus on the kinetic models suitable for describing these reactions. Section *.3 will show how to set up the reactor models and will also show the mass transport interactions need to be modeled. T...

Kinetic model for solid diffusion with a competing surface reaction

where 8, is the thickness of diffusant initially plated on the surface of the specimen, D is the diffusivity, and c(x, t) is atomic fraction of the diffusant at (x, t). This expression is appropriate if the diffusion anneal is long compared to mSo2/4Dc'„ where c, is the solubility of the diffusant. "' In some systems, this condition cannot be met. For example, in the study of the diffusion of z...

Kinetic Model of Coal Combustion

Catalytic Kinetic Determination of Silver through its Catalytic Effect on Congo Red-Peroxodisulphate Reaction

A kinetic-spectrophotometric procedure is reported for determination of trace amounts of Ag(I). This method is based on catalytic effect of silver ion on the oxidation of congo red by potassium peroxodisulphate at pH=3.4 and 30 oC in the presence of 1,10-phenanthroline as an activator. The reaction was followed spectrophotometrically by measuring the rate of change in absorbance ...

Mathematical Modeling of Fluorination Reaction of Uranium Dioxide and Evaluation of Existing Gas-Solid Reaction Models